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Category:solvents/deluents for cosmetic, flavor and/or fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | white crystals (est) |
| Assay: | 99.00 to 100.00
|
| Food Chemicals Codex Listed: | No |
| Melting Point: | 110.00 to 115.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 433.00 to 434.00 °C. @ 760.00 mm Hg
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| Flash Point: | 370.00 °F. TCC ( 187.78 °C. )
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| logP (o/w): | 0.630 |
| Soluble in: |
| | alcohol | | | ether | | | water, 1018 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| Odor Type: odorless |
| Odor Strength:none |
| Odor Description:at 100.00 %. odorless |
| Flavor Type: bitter |
| bitter citrus |
Taste Description: at 100.00 ppm. Bitters-like, with a citrus tonic flavor
Mosciano, Gerard P&F 16, No. 1, 31, (1991) |
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | None - None found. |
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
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| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
|
Not determined
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| Dermal Toxicity: |
|
Not determined
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| Inhalation Toxicity: |
|
Not determined
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Safety in Use Information:
| Category: | | solvents/deluents for cosmetic, flavor and/or fragrance agents |
| Recommendation for alpha-dextro-pentaacetyl glucose usage levels up to: | | | not for fragrance use.
|
| |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 1500.00000 |
| beverages(nonalcoholic): | - | 100.00000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | - |
| fruit ices: | - | - |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | - |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
References:
| | [2,3,5-triacetyloxy-6-(acetyloxymethyl)oxan-4-yl] acetate |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 79064 |
| Pubchem (sid): | 135036643 |
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| (2S,3R,4S,5R,6R)-6-( | acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate | | alpha-D- | glucopyranose pentaacetate | | alpha-dextro- | glucopyranose pentaacetate | | alpha-D- | glucose pentaacetate | | alpha-dextro- | glucose pentaacetate | | | hexopyranose, pentaacetate | | 1,2,3,4,6- | penta-O-acetyl-a-D-galactopyranose | | 1,2,3,4,6- | penta-O-acetyl-a-D-glucopyranose | | 1,2,3,4,6- | penta-O-acetyl-a-D-mannopyranose | | 1,2,3,4,6- | penta-O-acetylhexopyranose | | alpha-D- | pentaacetyl glucose | | alpha-dextro- | pentaacetyl glucose | | 1,2,3,4,6- | pentaacetyl-alpha-dextro-glucose | | alpha- | pentaacetyl-D-glucose | | alpha- | pentaacetyl-dextro-glucose | | [3,4,5,6- | tetrakis(acetyloxy)tetrahydro-2H-pyran-2-yl]methyl acetate | | 3,4,5- | triacetyloxy-6-(acetyloxymethyl)-2H-3,4,5,6-tetrahydropyran-2-yl acetate | | [2,3,5- | triacetyloxy-6-(acetyloxymethyl)oxan-4-yl] acetate |
Articles:
| PubMed:Insulin release: the receptor hypothesis. |
| PubMed:Deuterium-induced isotope effects on the 13C chemical shifts of α-D-glucose pentaacetate. |
| PubMed:Selective formation of glycosidic linkages of N-unsubstituted 4-hydroxyquinolin-2-(1H)-ones. |
| PubMed:Sugar acetates as CO2-philes: molecular interactions and structure aspects from absorption measurement using quartz crystal microbalance. |
| PubMed:A simple preparation of 2,3,4,6-tetra-o-acyl-gluco-, galacto- and mannopyranoses and relevant theoretical study. |
| PubMed:Preparation of nucleoside-carbohydrate phosphodiester prodrug analogues by chemoenzymatic procedure. |
| PubMed:Directed assembly of sub-nanometer thin organic materials with programmed-size nanopores. |
| PubMed:Measurement of gluconeogenesis using glucose fragments and mass spectrometry after ingestion of deuterium oxide. |
| PubMed:Characterization of a new rhamnogalacturonan acetyl esterase from Bacillus halodurans C-125 with a new putative carbohydrate binding domain. |
| PubMed:YesT: a new rhamnogalacturonan acetyl esterase from Bacillus subtilis. |
| PubMed:Examination of glass transitions in CO(2)-processed, peracetylated sugars using sum frequency generation spectroscopy. |
| PubMed:Mirror-image carbohydrates: synthesis of the unnatural enantiomer of a blood group trisaccharide. |
| PubMed:Monosaccharide esters: new tools in biomedicine. |
| PubMed:Monosaccharide esters: clinically relevant? |
| PubMed:Synthesis of 2-thiohydantoins and their S-glucosylated derivatives as potential antiviral and antitumor agents. |
| PubMed:Synthesis and antiperoxidant activity of new phenolic O-glycosides. |
| PubMed:Metabolism of alpha-D-[1,2-13C]glucose pentaacetate and alpha-D-glucose penta[2-13C]acetate in rat hepatocytes. |
| PubMed:Activation of glycogen synthase a in hepatocytes exposed to alpha-D-glucose pentaacetate. |
| PubMed:Stimulation of insulin synthesis and release by alpha-D-glucose pentaacetate in pancreatic islets from human subjects. |
| PubMed:Metabolism of D-[1,2-13C]glucose and alpha-D-[1,2-13C]glucose pentaacetate in tumoral pancreatic islet cells. |
| PubMed:Metabolism of d-glucose and its pentaacetate ester in muscles and pancreatic islets of GLUT4 null mice. |
| PubMed:Effect of D-mannoheptulose upon the cationic and secretory responses to alpha-D-glucose pentaacetate in perifused rat pancreatic islets. |
| PubMed:Differences in the time course of the metabolic response of B and non-B pancreatic islet cells to D-glucose and metabolized or non-metabolized hexose esters. |
| PubMed:Effects of extracellular pH upon the insulinotropic action of alpha-D-glucose pentaacetate. |
| PubMed:Isomeric and anomeric specificity of the metabolic and secretory response of rat pancreatic islets to glucose pentaacetate. |
| PubMed:Regioselective hydrolysis of peracetylated alpha-D-glycopyranose catalyzed by immobilized lipases in aqueous medium. A facile preparation of useful intermediates for oligosaccharide synthesis. |
| PubMed:Insulinotropic action of monosaccharide esters: therapeutic perspectives. |
| PubMed:Opposite effects of D-glucose pentaacetate and D-galactose pentaacetate anomers on insulin release evoked by succinic acid dimethyl ester in rat pancreatic islets. |
| PubMed:Effects of alpha-D- and beta-L-glucose pentaacetate on effluent radioactivity from pancreatic islets labelled with [(32)P]phosphate and myo-[2-(3)H]inositol. |
| PubMed:Effects of artificial sweeteners on insulin release and cationic fluxes in rat pancreatic islets. |
| PubMed:Effects of hexose pentaacetates on electrical activity and cytosolic Ca2+ in mouse pancreatic islets. |
| PubMed:Failure of streptozotocin tetraacetate to undergo extensive hydrolysis and to inhibit D-glucose metabolism and insulinotropic action in rat pancreatic islets. |
| PubMed:The riddle of L-glucose pentaacetate insulinotropic action (review). |
| PubMed:Insulinotropic action of the polyacetate esters of two non-nutrient monosaccharides in normal and diabetic rats. |
| PubMed:Insulinotropic action of beta-L-glucose pentaacetate. |
| PubMed:Monosaccharide esters: new tools in biomedical research. |
| PubMed:Hydrolysis of hexose pentaacetate esters in rat pancreatic islets. |
| PubMed:Dual mode of action of glucose pentaacetates on hormonal secretion from the isolated perfused rat pancreas. |
| PubMed:Comparison of the effects of D-mannoheptulose and its hexaacetate ester on D-glucose metabolism and insulinotropic action in rat pancreatic islets. |
| PubMed:Insulinotropic action of alpha-D-glucose pentaacetate: metabolic aspects. |
| PubMed:Stimulation by hexose esters of lactate production by rat erythrocytes: insensitivity to 3-O-methyl-D-glucose and inhibition by 2-deoxy-D-glucose and its tetraacetic ester. |
| PubMed:Resistance of the insulinotropic action of alpha-D-glucose and beta-L-glucose pentaacetates to cholera and pertussis toxins. |
| PubMed:Synergistic insulinotropic action of succinate, acetate, and glucose esters in islets from normal and diabetic rats. |
| PubMed:Insulinotropic action of the polyacetate esters of metabolized and non-metabolized monosaccharides in pancreatic islets from normal and diabetic rats. |
| PubMed:Bitter taste of monosaccharide pentaacetate esters. |
| PubMed:Insulinotropic action of alpha-D-glucose pentaacetate: functional aspects. |
| PubMed:Stimulation of insulin release by alpha-D-glucose pentaacetate. |
| PubMed:SW.B6-Soa(b) nontaster congenic strains completed and a sucrose octaacetate congenic quartet tested with other bitters. |
| PubMed:Mass isotopomer pattern and precursor-product relationship. |
| PubMed:Esterase Activities of Fibrobacter succinogenes subsp. succinogenes S85. |
| PubMed:Preparation of various glucose esters via lipase-catalyzed hydrolysis of glucose pentaacetate. |
| PubMed:Rapid and specific isolation of radioactive glucose from biological samples. |
| PubMed:Utilization of propionic acid by the L4 and adult stages of Cooperia punctata (Nematoda: Trichostrongylidae) grown in vitro. |
| PubMed:Rapid determination of (carbon-14) glucose specific radioactivity for in vivo glucose kinetics. |
| PubMed:DETERMINATION OF THE SPECIFIC ACTIVITY OF LABELED BLOOD GLUCOSE BY LIQUID SCINTILLATION USING GLUCOSE PENTAACETATE. |
| PubMed:The suitability of beta-D-glucose pentaacetate for food use. I. The subscute toxicity of beta-D-glucose pentaacete. |
| PubMed:The suitability of beta-D-glucose pentaacetate for food use. II. Studies on the absorption and metabolism. |
| PubMed:Action of the Grignard reagent on beta-d-glucose pentaacetate. |
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3D/inchi