EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

trimethylolpropane triacrylate
2-propenoic acid, 2-ethyl-2-(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester

Supplier Sponsors

Name:2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate
CAS Number: 15625-89-5Picture of molecule3D/inchi
Other(deleted CASRN):100465-65-4
ECHA EINECS - REACH Pre-Reg:239-701-3
FDA UNII: 4B67KGL96S
Nikkaji Web:J38.143H
MDL:MFCD00008628
XlogP3-AA:2.70 (est)
Molecular Weight:296.31960000
Formula:C15 H20 O6
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:hair fixing agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:colorless to tan liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.10000 @ 25.00 °C.
Boiling Point: 380.90 °C. @ 760.00 mm Hg (est)
Vapor Pressure:5.900000 mmHg @ 25.00 °C. (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 1.500 (est)
Soluble in:
 water, 46.31 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: film formers
hair conditioning
hair fixing agents
 
Suppliers:
BOC Sciences
For experimental / research use only.
Trimethylolpropane triacrylate 95%
Connect Chemicals
Trimethylolpropane triacrylate (TMPTA)
Odor: characteristic
Use: TMPTA is an aliphatic trifunctional acrylate of low viscosity and excellent crosslinking reactivity. It is an effective reactive diluent with excellent solvency and viscosity reducing characteristics in UV/EB curable formulations based on epoxy, polyurethane and polyesters. TMPTA is widely used in coatings and varnishes. It gives very good chemical and physical properties to the system at the appropriate concentration. TMPTA enhance the performance of the coating on sensitive substrates (like plastics) and rigid irregular surfaces (like wood).
Kowa Amerian Corporation
TMPTA
Odor: characteristic
Use: TMPTA is a trifunctional monomer used in the manufacture of plastics, adhesives, acrylic glue, anaerobic sealants, and ink. It is useful for its low volatility and fast cure response. It has the property of resistance against weather, chemical, water and abrasion.
Santa Cruz Biotechnology
For experimental / research use only.
Trimethylolpropane Triacrylate
Sigma-Aldrich: Aldrich
For experimental / research use only.
Trimethylolpropane Triacrylate
sds
TCI AMERICA
For experimental / research use only.
Trimethylolpropane Triacrylate >75.0%(GC)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intraperitoneal-rat LD50 55 mg/kg
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: ATAXIA
National Technical Information Service. Vol. OTS0555702

oral-rat LD50 5190 uL/kg
Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.

Dermal Toxicity:
skin-rabbit LD50 5170 mg/kg
American Industrial Hygiene Association Journal. Vol. 42(11), Pg. B53, 1981.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
hair fixing agents
Recommendation for trimethylolpropane triacrylate usage levels up to:
 not for fragrance use.
 
Recommendation for trimethylolpropane triacrylate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):15625-89-5
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :27423
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate
Chemidplus:0015625895
RTECS:AT4810000 for cas# 15625-89-5
 
References:
 2,2-bis(prop-2-enoyloxymethyl)butyl prop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:15625-89-5
Pubchem (cid):27423
Pubchem (sid):134991538
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C14537
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.12.5050
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 acrylic acid, 1,1,1-(trihydroxymethyl)propane triester
 acrylic acid, triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol
2-ethyl-2-(((1-oxoallyl)oxy)methyl)-1,3-propanediyl diacrylate
2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate
 ogumont T 200
1,3-propanediol, 2-ethyl-2-(hydroxymethyl)-, triacrylate
2-propenoic acid, 1,1'-(2-ethyl-2-(((1-oxo-2-propen-1-yl)oxy)methyl)-1,3-propanediyl) ester
2-propenoic acid, 2-ethyl-2-(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester
 saret 351
 sartomer SR 351
 setalux UV 2241
 trimethylol propane triacrylate
 trimethylolpropane triacrylate
 viscoat 295
 

Articles:

PubMed:In situ polymerization of monolith based on poly(Triallyl Isocyanurate-co-trimethylolpropane triacrylate) and its application in high-performance liquid chromatography.
PubMed:One-step interfacial thiol-ene photopolymerization for metal nanoparticle-decorated microcapsules (MNP@MCs).
PubMed:Beauty of lotus is more than skin deep: highly buoyant superhydrophobic films.
PubMed:The first photochemical in situ production of Ti-based nanoparticles: a SH2 strategy using bis(cyclopentadienyl)titanium dichloride (Cp2TiCl2).
PubMed:Stacked quantum dot embedded silica film on a phosphor plate for superior performance of white light-emitting diodes.
PubMed:Preparation and characterization of poly(triallyl isocyanurate-co-trimethylolpropane triacrylate) monolith and its applications in the separation of small molecules by liquid chromatography.
PubMed:Species and gender differences in the carcinogenic activity of trimethylolpropane triacrylate in rats and mice.
PubMed:Osmocapsules for direct measurement of osmotic strength.
PubMed:Preparation of a novel porous poly (trimethylol propane triacrylate-co-ethylene dimethacrylate) monolithic column for highly efficient HPLC separations of small molecules.
PubMed:High-performance liquid chromatography separation of small molecules on a porous poly (trimethylol propane triacrylate-co-N-isopropylacrylamide-co-ethylene dimethacrylate) monolithic column.
PubMed:Factors affecting the TMPTA radical polymerization photoinitiated by phenyltrialkylborates paired with tri-cationic hemicyanine dye. Kinetic studies.
PubMed:Poly(ester amine) synthesized from trimethylolpropane triacrylate and spermine as an efficient siRNA carrier.
PubMed:Hole-shell microparticles from controllably evolved double emulsions.
PubMed:Thiol-acrylate nanocomposite foams for critical size bone defect repair: A novel biomaterial.
PubMed:Responsive hybrid microcapsules by the one-step interfacial thiol-ene photopolymerization.
PubMed:Toxicology and carcinogenesis studies of trimethylolpropane triacrylate (technical grade) (CASRN 15625-89-5) in F344/N rats and B6C3F1/N mice (dermal studies).
PubMed:Two decades of occupational (meth)acrylate patch test results and focus on isobornyl acrylate.
PubMed:Imprintable, bendable, and shape-conformable polymer electrolytes for versatile-shaped lithium-ion batteries.
PubMed:High Throughput Micropatterning of Optical Oxygen Sensor for Single Cell Analysis.
PubMed:Enhanced two-photon excited fluorescence in three-dimensionally crosslinked bovine serum albumin microstructures.
PubMed:Surface-tension-induced synthesis of complex particles using confined polymeric fluids.
PubMed:High performance magnetically controllable microturbines.
PubMed:Flow-through immunosensors using antibody-immobilized polymer monoliths.
PubMed:Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating.
PubMed:Ring-opening metathesis polymerization based pore-size-selective functionalization of glycidyl methacrylate based monolithic media: access to size-stable nanoparticles for ligand-free metal catalysis.
PubMed:Altering amine basicities in biodegradable branched polycationic polymers for nonviral gene delivery.
PubMed:Asthma induced by a thermal printer.
PubMed:Tuning curvature in flow lithography: a new class of concave/convex particles.
PubMed:Occupational conjunctivitis as the sole manifestation of airborne contact allergy to trimethylolpropane triacrylate contained in a UV-cured paint.
PubMed:Electron beam triggered, free radical polymerization-derived monolithic capillary columns for high-performance liquid chromatography.
PubMed:Toxicology studies of trimethylolpropane triacrylate (technical grade) (CAS No. 15625-89-5) in F344/N rats, B6C3F1 mice, and genetically modified (FVB Tg.AC hemizygous) mice (dermal studies).
PubMed:Surface functionalization of ZrO2 nanocrystallites for the integration into acrylate nanocomposite films.
PubMed:Optofluidic encapsulation of crystalline colloidal arrays into spherical membrane.
PubMed:Photocurable pickering emulsion for colloidal particles with structural complexity.
PubMed:Comparative study on the separation behavior of monolithic columns prepared via ring-opening metathesis polymerization and via electron beam irradiation triggered free radical polymerization for proteins.
PubMed:Facile approach to the fabrication of a micropattern possessing nanoscale substructure.
PubMed:Separation behavior of electron-beam curing derived, acrylate-based monoliths.
PubMed:Stilbene-like molecules as fluorescent probes applied for monitoring of polymerization process.
PubMed:Integration of zinc oxide nanoparticles into transparent poly(butanediolmonoacrylate) via photopolymerisation.
PubMed:Evaluation of hyperbranched poly(amino ester)s of amine constitutions similar to polyethylenimine for DNA delivery.
PubMed:Topical application of representative multifunctional acrylates produced proliferative and inflammatory lesions in F344/N rats and B6C3F1 mice, and squamous cell neoplasms in Tg.AC mice.
PubMed:Allergic contact dermatitis from trimethylolpropane triacrylate and pentaerythritol triacrylate.
PubMed:An in vitro wear study of posterior denture tooth materials on human enamel.
PubMed:Highly cross-linked networks for dental applications obtained by photocuring of tris[2-(acryloyloxy)ethyl]isocyanurate, 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate, and pentaerythritol triacrylate.
PubMed:Beaded reactive polymers. 3. Effect of triacrylates as crosslinkers on the physical properties of glycidyl methacrylate copolymers and immobilization of penicillin G acylase.
PubMed:Airborne occupational allergic contact dermatitis due to trimethylolpropane triacrylate (TMPTA) used in the manufacture of printed circuit boards.
PubMed:10 years of patch testing with the (meth)acrylate series.
PubMed:Preparation of an effective light-cured bonding agent for orthodontic application.
PubMed:Photopolymerized multifunctional (meth)acrylates as model polymers for dental applications.
PubMed:Occupational allergic contact dermatitis and contact urticaria caused by polyfunctional aziridine hardener.
PubMed:Densely crosslinked polymer networks of poly(ethylene glycol) in trimethylolpropane triacrylate for cell-adhesion-resistant surfaces.
PubMed:Polymer networks with grafted cell adhesion peptides for highly biospecific cell adhesive substrates.
PubMed:Permeation of multifunctional acrylates through selected protective glove materials.
PubMed:Genotoxicity of multifunctional acrylates in the Salmonella/mammalian-microsome assay and mouse lymphoma TK+/-assay.
PubMed:Lack of genotoxicity of cross-linked acrylate polymers in four short-term genotoxicity assays.
PubMed:Comparison of mutagenicity results for nine compounds evaluated at the hgprt locus in the standard and suspension CHO assays.
PubMed:[A light-cured acrylic adhesive for fixing resin retention devices to the wax pattern].
PubMed:Differential mutant quantitation at the mouse lymphoma tk and CHO hgprt loci.
PubMed:Analysis of the genotoxicity of nine acrylate/methacrylate compounds in L5178Y mouse lymphoma cells.
PubMed:Immunogenicity of acrylate chemicals as assessed by antibody induction.
PubMed:Allergic contact dermatitis from UV-curing acrylate in the manufacture of optical fibres.
PubMed:Dermatitis from aziridine hardener in printing ink.
PubMed:Contact allergy to aziridine paint hardener.
PubMed:Dermatitis from trimethylolpropane triacrylate.
PubMed:The sensitizing capacity of multifunctional acrylates in the guinea pig.
PubMed:Allergic contact dermatitis due to urethane acrylate in ultraviolet cured inks.
PubMed:Contact allergy to trimethylolpropane triacrylate (TMPTA) in an aziridine plastic hardener.
PubMed:Trimethylolpropane triacrylate.
PubMed:Allergic contact dermatitis from acrylates in ultraviolet curing inks.
PubMed:Allergenicity of trimethylol propane triacrylate in ultraviolet curing inks in the guinea pig.
 
Notes:
acrylate derivative found in ultraviolet curing inks; causes contact dermatitis.
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